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Macro mineral function, deficiency and toxicity symptoms. (Source: Ensminger, M.D., Oldfied, J.E. and Heinemann, W.W. 1990.

Mineral  Function  Deficiency Symptoms  Toxicity Symptoms 
Calcium (Ca)  Bone and teeth formation, muscle contractions, milk production.  Rickets (young), milk fever, osteomalacia.  Altered calcium to phosphorus ratio affects bone development and bone structure. 
Phosphorus (P)  Bone and teeth formation, energy metabolism, DNA makeup, enzyme systems.  Rickets (young), osteomalacia, depraved appetite (pica), low conception rates.  Altered calcium to phosphorus ratio affects bone developments and bone structure. 
Magnesium (Mg)  Normal bone development, enzyme activator  Hyperirritability (tetany, grass staggers), vasodilation (reduced blood pressure).  Upset Ca:P metabolism. 
Sodium (Na)  Involved in cellular acid/base balance, muscle contractions, making bile.  Reduced growth and production levels, decreased reproduction.  Salt toxicity (blind staggers), hypertension. 
Chlorine (Cl)  Involved in cellular acid/base balance, gastric juices (hydrochloric acid.  Decreased growth rate.  other component of salt (sodium chloride). Not considered problematic. 
Potassium (K)  Cellular osmotic pressure, muscle activity, enzymes, carbohydrate metabolism.  Retarded growth, unsteady walk, muscle weakness, pica diarrhea, abomasum extended.  Low Mg with high K results in excess K in urine. High K will interfere with Mg absorption. 
Sulfur (S)  Required in sulfur containing amino acids (cysteine, methionine), lipid metabolism, carbohydrate and energy metabolism.  Retarded growth (sulfur containing amino acid shortage).  Not consedered problematic.